When shooting black and white photography using natural light, you should let the situation dictate the look and feel of the photo. So don't set out and try to shoot a high contrast shot unless you find a good opportunity with the right lighting. Try shooting on an overcast day.

The natural contrasts that come with black and white photography really bring into focus the texture of certain surfaces such as skin, fur, dirt, metal, wood, etc. in a way that color photography simply doesn't.

White balance (WB) is the process of removing unrealistic color casts, so that objects which appear white in person are rendered white in your photo. Proper camera white balance has to take into account the "color temperature" of a light source, which refers to the relative warmth or coolness of white light.